Salt and the Boiling Point of Water

Boiling point elevationColligative properties determine how a solvent will behave once it becomes a solution. The degree of change depends on the amount of solute dissolved in the bulk liquid, not the type of solute. So, without my doing your homework for you…how does adding salt to water affect its boiling point? You will find several clues and several keywords above and below.

The fact that dissolving a salt in a liquid, such as water, affects its boiling point comes under the general heading of colligative properties in chemistry. In fact, it’s a generic phenomenon dissolve one substance (the solute) in another (the solvent) and you will raise its boiling point.

So, here’s a rough explanation of what’s going on. If a substance has a lower vapour pressure than the liquid (it’s relatively non-volatile in other words) then dissolving that substance in the liquid, common salt (NaCl) in water (H2O), for instance, will lower the overall vapour pressure of the resulting solution compared with the pure liquid. A lower vapour pressure means that the solution has to be heated more than the pure liquid to make its molecules vaporise. It is an effect of the dilution of the solvent in the presence of a solute. If you want to know about tungsten and why it is used in incandescent light bulbs please check out the Wikipedia entry.

Put another way, if a solute is dissolved in a solvent, then the number of solvent molecules at the surface of the solution is less than for pure solvent. The surface molecules can thus be considered “diluted” by the less volatile particles of solute. The rate of exchange between solvent in the solution and in the air above the solution is lower (vapour pressure of the solvent is reduced). A lower vapour pressure means that a higher temperature is necessary to boil the water in the solution, hence boiling-point elevation.

Conversely, adding common salt to water will lower its freezing point. This effect is exploited in cold weather when adding grit (rock salt) to the roads. The salt dissolves in the water condensing on the road surface and lowers its freezing point so that the temperature has to fall that bit more before ice will form on the roads.

A much more fun use for freezing point depression is to add salt to ice to make ice cream. The About site has some instructions on how to do this, although it’s probably not too tasty.

Curiously, at least one Sciencebase reader was searching for the phrase “how does sugar affect the boiling point of water?” and landed on this page. This is essentially the same question as, “does salt affect the boiling point of water?”. The nature of the solute, the material being dissolved in the solvent, is pretty much irrelevant at a first estimate. Rather, it is the amount of material that is dissolved (which depends on the materials solubility) that influences the boiling and freezing points as described above.

Now, check out this great science project you can download now that includes A Pinch of Salt which will help you answer that question.

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149 thoughts on “Salt and the Boiling Point of Water

  1. i would like to know what is the effect of salt on boiling point of mixture of solvents (ammonia+water).The last sentence in the first paragraph of your post doesn’t mention that there is a maximum, it is not a linear scale, it tends towards a maximum value, in other words it plateaus. Solubility curves also complicate the picture. Remember the solubility curve for NaCl is unusual, as it’s solubility hardly varies with temperature whereas it does for other salts.4 cups of wate and 3 tbs of salt

    plzzzzzz!!!.Hey, “Somebody”, of what would your science teachers and judges be suspicious? The fact that you were planning to crib the entire article and claim it as your own (in which case you’ll not get a great grade anyway because the article isn’t a project write-up)? Or, the fact that you’d had the initiative to search for useful background information on the internet? The article exists on this site because lots of people want to know how salt affects the boiling point of water, I have no intention of changing.

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