Converting Carbon Dioxide

Drax power station cooling towers photo by David Bradley“Nothing beats finding vast lakes of oil for the pumping, or vast deposits of coal for the digging; thanks mother nature!” proclaimed Craig Grimes of Penn State University in an emailed response to my skeptical question regarding his work on catalysts that can convert the greenhouse gas carbon dioxide into a fuel, methane.

I report on his fascinating work in the March issue of Intute Spotlight. The process involves using solar power to chemically reduce carbon dioxide back to a combustible hydrocarbon. Grimes suggests that a flow system employed on fossil fuel burning power station chimney stacks could scrub out the carbon dioxide before it enters the atmosphere and provide us with a viable additional energy source.

Playing devil’s advocate, my skepticism was regarding the energy required to produce the catalysts, which are composed of relatively rare minerals, to build and maintain the plant and to decommission it at end-of-life. There are also the costs of actually trapping the carbon dioxide and then transporting the methane produced to sites where it is needed. Moreover, burning that methane then releases the carbon dioxide elsewhere, so it’s not a quick fix.

Grimes retorts that, “The idea is we better start figuring out how to not put carbon dioxide into the atmosphere, and begin to anticipate that our vast lakes of oil and vast deposits of coal are finite. Solar energy is not finite, at least in any conventional sense, but it is diffuse. There are lots of pitfalls with renewable energy sources, which is why coal and oil are cheaper to buy and use,” he told me. “Yes, you have to make the materials, install them, etc. All of that takes time, energy and money. However, outside of praying for a miracle, i.e. Having a faith-based energy policy, we would be well put to start trying to come up with an alternative to coal and oil.”

I also asked Grimes whether the same system might be used to process carbon dioxide sequestered from the atmosphere directly. “Yes, carbon dioxide that is to be ‘buried’ could instead be used as feedstock for the process, so its win win,” he told me. “The idea is not to burn the methane venting it back in to the atmosphere. You burn, collect, recycle, burn, collect, recycle…”

My Intute Spotlight column has an entirely environmental theme this month. Alongside my report on Grimes’ carbon conversion catalysts, we have a write-up on the recent modelling of Antarctic cooling 35 million years ago and a report on new materials that can efficiently extract hydrogen gas from mixtures and so might fuel a future hydrogen economy.

Research Blogging IconOomman K. Varghese, Maggie Paulose, Thomas J. LaTempa, Craig A. Grimes (2009). High-Rate Solar Photocatalytic Conversion of CO2 and Water Vapor to Hydrocarbon Fuels Nano Letters, 9 (2), 731-737 DOI: 10.1021/nl803258p

Baffling Fluid Dynamics

hurricaneDuring my student days, one of the most obviously complicated and beyond-comprehension modules was that on fluid dynamics. It’s not surprising that it was complicated and beyond comprehension, the way fluids (gases and liquids by definition) move is not simple.

There is no single, straightforward equation that can describe the flow of water cascading down waterfall. No clear-cut algorithm can determine exactly how oil will flow in an Alaskan pipeline. Mathematics and science struggle to predict the precise path of hurricanes and tornadoes. And, even tracking a water drop trickling down the back of Jeff Goldblum’s hand is off-limits. And, if you’ve ever tried to explain to a child how a plane becomes airborne and once at altitude doesn’t just fall out of the sky you will know that nothing about fluid mechanics is ever easy.

Of course, there are equations that describe fluid motion and while some of these are incredibly sophisticated they are far from perfect. There are the Bernouilli equations, for instance, which students (and professors) of the physical sciences struggle over to this day.

niagara-fallsUnderstanding how fluids move may seem trivial to the uninitiated if all it were about was predicting which way a water drop will fall. But, my allusion to hurricanes, planes and pipelines hopefully hints at just how important understanding fluid mechanics is. Fluid mechanics is a matter of life or death. A rather prosaic-sounding research paper entitled “Analytical and numerical analysis of the liquid longitudinal sloshing impact on a partially filled tank-vehicle with and without baffles” is testament to this fact.

At first glance, I have to admit I thought it was about improving efficiency at vehicle filling stations, but co-author of the paper Marc Richard of the Department of Mechanical Engineering, at the University Laval, in Québec, Canada, explained that it’s about improving the safety of tanker trucks. The kind of heavy-goods vehicles that weigh several tonnes, and carry highly combustible liquids such as petroleum, volatile and toxic organic solvents, and liquid food stuffs.

Picture the scene, it’s a wet and foggy night, a truck driver pulling a half-load of product from factory to outlet, takes a bend too quickly, swerves to avoid an oncoming vehicle and in the dazzling glare of headlights and spray veers off the road heading for a ditch.

The thousands of litres of liquid sloshing around in the half-filled tank follow all the right equations of fluid mechanics and some of the wrong ones. The combined momentum of those billions upon billions of organic molecules attempt to shove the truck and its tank-trailer one way, while the dwindling friction between wheels and wet road attempt to shove it another.

oil-tanker-crashThe inevitable outcome of this fluid reaction is a truck spinning out of control and overturning is it smashes into the ditch. The endpoint will depend on whether the truck was transporting an inflammable, volatile, and toxic load or full-fat cola.

Marc Richard and colleagues Messaoud Toumi and Mohamed Bouazara of the University of Quebec at Chicoutimi, want to inhibit this kind of out of control fluid mechanics. They are investigating the design of in-tank baffles that can smooth the sloshing of the fluid within. Whether a tanker truck goes out of control on a wet and foggy night, when a tire blows, or in a vehicle collision, these baffles will make the motion of the liquid load that much more predictable and perhaps give the driver a split second in which to recover control averting disaster.

At this point it would be easy to wax lyrical about the moral of the tale and persuade students everywhere to persist with their fluid mechanics studies. However, I suspect that no amount of persuading would encourage more than a few to consider hydrostatic pressure, incompressible fluids, and orifice baffles as anything but beyond comprehension.

Research Blogging IconM. Toumi, M. Bouazara, M.J. Richard (2008). Analytical and numerical analysis of the liquid longitudinal sloshing impact on a partially filled tank-vehicle with and without baffles International Journal of Vehicle Systems Modelling and Testing, 3 (3), 229-249

Wireless Probing, Shiny Bugs, Remote Scanning

brain-probeProbing the brain wirelessly – IR-absorbing lead selenide particles form the basis of a method for the study of neuronal activation in samples of brain tissues without the need for hard-wired electrodes. The technique instead utilises light-triggered nanostructured semiconductor photoelectrodes to probe activity.

Propagation improves MRI, allows remote scanning – Swiss researchers have succeeded in exciting and imaging nuclear magnetic resonance in the human body in a way that could represent a paradigm shift for imaging.

Plug and play molecular logic – A “plug and play” approach to building molecular logic units has been developed by chemists in the UK and Thailand. The team used various spectroscopic techniques, including fluorescence and NMR to monitor their logical constructions.

White light microscope – Silver nanoparticles that can generate white light could improve microscopy in research into cancer and bone diseases according to a paper in the March issue of Nano Letters.

Crystal structure not to be sneezed at – Researchers have obtained the X-ray crystal structure of a monoclonal antibody (mAb) bound to the lethal H5N1 strain of avian influenza virus A. The structure reveals that the heavy chain of the mAb inserts into a highly conserved pocket in the of the haemagglutinin protein stem.

Sperm assessment – Raman spectroscopy could enable fertility researchers and IVF clinicians to assess individual sperm. The process involves capturing an individual sperm cell between two highly focused beams of laser light with Raman pinning down features of the trapped wriggler’s DNA.

Scientific Locations Mapped

scientific-locationsI’ve made a Google map showing important scientific locations – scientific locations.

Recently, a fellow singer in the Cottenham Big Mouth collective was telling me about a Google map he’d created with all his favourite eateries that do live jazz, sounded groovy man…but although I love food and don’t mind a bit of jazz, I thought Sciencebase readers would prefer something a little more…well…science based. So, I’ve created Scientific Locations.

Scientific locations is a map that will grow steadily to add pins and notes to sites like the Cambridge U’s Cavendish Laboratory, Darwin’s Down House, Chicago Pile #1 and more. In other words, it’s going to show the sites associated with some of the greatest scientific discoveries including the discovery of the electron, the origin of species, and the development of the world’s first artificial nuclear reactor.

I gave the Scientific Locations map a shout out on twitter, hoping not to hear that someone else had already taken on such a monumental task. So far no one has told me that I’m reinventing the wheel, so to speak. If anyone happens to know precisely where the wheel was invented I’ll pin that on the map, of course.

Adrian Kybett ChemTwittChem on Twitter has sent me several pins early in the campaign and the map was growing steadily. Then BadAstronomer, Grace_Baynes, Disco_Dave, BuffaloDavid, Krelnik, IYA_US, mactavish, DiscoveryChPR, and many others began to retweet the link bringing in many more suggestions from Ytterby to Derbyshire and beyond.

The official Google Lunar X PRIZE Twitter account also gave me a shout out and pointed to a related collaborative map. Ricardo Vidal also pointed me to a map showing all the labs taking part in Open WetWare

If you have any ideas for scientific locations, please leave a comment here, send me an email, or tweet me. I’ll add a credit (by way of your twitter link or web site) to the map pin for original ideas.

You Can Call Me Al

jim-al-khaliliAlgebra, alchemy, alcohol, aldebaran, alkali, Alhambra, algorithm, Algarve, and, of course, albatross.

One thing in common…they’re all “al” words, and what is “al” you ask? It’s simply the Arabic definite article, it’s the “the”, in other words. Which means that all those words have “the” in their etymology.

So, when Sir Isaac Newton was referred to as an Alchemist, it didn’t necessarily mean he was searching for the philosopher’s stone or weaving the philosopher’s wool to convert base metal into gold or create an elixir of youth, he was merely studying “the” chemistry. There was no real distinction at the time, although he did partake of some odd practices nevertheless…allegedly.

The BBC recently broadcast an excellent series on Science and Islam showing how those “al” words underpin much of modern science. It was narrated by physicist Jim Al Khalili of the University of Surrey, given his name, his enthusiasms, and his science, how could it not be?

In case you are wondering, Al Khalil loosely means The Friend of God, the “i” at the end makes it possessive, so more accurately, it is “My Friend of God”.