Top Ten Science News Posts

xmas-decorationsIt’s that time of year again. The shops have been full of Xmas crap joy for weeks, as have I, of course. The neighbours have been through Osram’s full stock twice with their religiously ambiguous, exterior decor, and now I’m filling a Sciencebase blog post with the classic end of year round up – the top ten list of science posts.

Far and away the winner, was the original post in which I broke the news of the melamine in milk scandal. I had to revisit the issue several times because of public demand for more and more information and so have clumped the various posts on melamine into a joint-first placement. The posts are drawing the crowds still, with hundreds of readers every day.

Close on the heels of the lowliest melamine post is one of the perennial educational favourites

Apologies for the previous version of this post, it seems I inadvertently published the autosaved draft in WordPress.

Dioxins in Pork

dioxin-pigDioxins Before Swine – Irish pork is off the menu, according to the BBC.

The UK’s Food Standards Agency is monitoring pork products in the Irish Republic because of fears of contamination with dioxins. “Tests showed some pork products contained up to 200 times more dioxins than the recognised safety limit.” Interestingly, dioxin levels in soil have been declining in recent years, according to another BBC report from 2007. The alert over dioxins followed an alert after PCBs (polychlorinated biphenyls) were reported to have been found in Irish pork on 1st December after samples were taken 19th November.

There is some hint that machine lubricating oils contaminated with PCBs (stable polychlorinated biphenyls) may have degraded to release dioxins which somehow found their way into the pig feed. But, more likely is that non-feed grade oil is being used at some point in the cycle to dry biscuit meal (out of date biscuits and bakery goods from the food industry). Such non-feed oils obviously do not have the same quality controls as extra virgin olive oil and so could very easily have higher than food-safe levels of contaminants, including PCBs and dioxins. This suggestion hints once again, as did the ongoing melamine scandal, at how easy it seems to be for unscrupulous sectors of the food industry to use non-food materials in their products, allegedly.

So, what are dioxins and should we be worried about them?

DioxinDioxins are organic compounds formed when a huge range of materials, particularly chlorinated polymers (PVC plastics) burn and in some industrial processes. They are ubiquitous in the environment and became the focus of environmental activism because of their reputation for being among the most toxic compounds known. Colloquially “dioxin” is talked of as if it were a single compound rather than a class of compounds, but the most usual reference is to the chlorine-containing compound 2,3,6,7-tetrachlorodibenzodioxin. Dioxins should not be confused with the compound 1,2-dioxin and 1,4-dioxin, which are heterocyclic, organic, antiaromatic compounds.

2,3,6,7-Tetrachlorodibenzodioxin can have some nasty effects such as irritation to the eyes, allergic dermatitis, chloracne, porphyria; gastrointestinal disturbance, possible reproductive, teratogenic effects, liver, kidney damage, haemorrhage, and occupational carcinogenicity. But, does that long list of problems mean anyone eating any of the food products from Ireland – bacon, ham, sausages, white pudding and pizzas with ham toppings – were or are in any danger. “The UK’s Food Standards Agency said it did not believe at this stage that UK consumers faced any ‘significant risk’,” reports the BBC. Seems like fair comment, only serious chronic exposure to low levels of dioxins or acute high-level exposure are of real concern.

No member of the public has ever died from dioxin poisoning, despite the fact that for several decades industry has been inadvertently releasing these materials into the environment as impurities in hundreds of products and that countless burning materials release the same supposedly deadly compounds across the globe continuously. Occupational exposure has led to probably at most four deaths from industrial accidents involving the release of dioxins, according to John Emsley writing in The Consumer’s Good Chemical Guide.

Flu Structure, Mp3s, and Magnetic Minestrone

You can read my latest science news updates in spectroscopynow.com:

One flu over – X-ray studies have revealed details of the structure of a protein used by the avian influenza, H5N1, that allows it to hide its RNA from the infected host’s immune system. The structure could provide a new target for the development of antiviral drugs against this potentially lethal virus

Minestrone and magnetic resonance – Researchers in the US and France may have overturned decades of theory in magnetic resonance studies by spotting a discrepancy in the way nuclear spins behave. Their new mathematical model of the process improves our understanding of atomic behaviour and could lead to better NMR spectra, sharper magnetic resonance images, and perhaps one day a fully portable MRI machine.

Organic soil matters – Could the earth beneath our feet hold the key to climate change? According to scientists at the University of Toronto Scarborough their NMR results show that global warming is changing the molecular structure of organic matter in soil.

Battery capacity is full of holes – Researchers in Korea have developed a novel material for the anode in rechargeable batteries, which they say could make them much more efficient and extend significantly the length of time between charges.

And on ChemWeb for science news with a chemical element:

First on the list in this week’s Alchemist, more on the new anode material, which is potentially good news for the iPod generation. In analytical research, HPLC has been used to spot dummy tequila and in medical chemistry US radiologists suggest that a dose of modified vitamin D could protect citizens from a dirty bomb attack. Next up, a new approach to addressing qubits allows for faster measurements that could take us a step closer to a quantum computer, while Yorkshire chemists are working out the best mix of starting materials to get the maximum height yield on their tasty products. Finally, this week’s award is a record breaker in the State where big is everything.

Top Ten Mutants

dna-testIf you ever thought genetics was only about disease, then check out the popular SNPs list on SNPedia. A SNP (pronounced “snip”) is a single nucleotide polymorphism, which in BradSpeak(TM) is basically a difference in a bit of your DNA that makes you different from the rest.

Anyway, here’s the Top Five SNPs that might be described as having no obvious direct medical importance.

  • rs1815739 sprinters vs endurance athletes (I reckon I lack both)
  • rs7495174 green eye color and rs12913832 for blue eye color
  • rs6152 can prevent baldness (this was discovered far too late for me)
  • rs1805009 determines red hair (some “comedians” might suggest this be swapped to the second list below)
  • rs17822931 determines earwax (and presumably how well your ears stay clear of insect infestation)

And, here’s the more sober list of SNPs that could have serious medical implications should you happen to discover you have one of these when you have your genome read by the likes of 23andMe.

  • rs9939609 triggers obesity (not a genetic excuse for eating too much)
  • rs662799 prevents weight gain from high fat diets (ditto)
  • rs4420638 and rs429358 can raise the risk of Alzheimer’s disease by tenfold or more
  • rs7903146 and rs12255372 linked to type-2 diabetes, the latter also to breast cancer
  • rs324650 influences alcohol dependence, rs1799971 makes alcohol cravings stronger (it would not be funny to say, “Mine’s a pint, with a whisky chaser”, right now)

It was a twitter discussion between SNP experts mza and attilacsordas that led me to the SNP list.

Shedding Light on Neon Signs

neon-signAs regular readers know, I like to keep a fairly close eye on what Sciencebase visitors are searching for so that I can put together new posts that provide answers to the questions readers want answering. Recently, there has been a spate of search queries related to neon signs. Perhaps not the most exciting of subjects, but there is some nice chemistry to be learned from all the different colours available, so I thought I’d shed some light on the subject of noble gas illumination.

Incidentally, for those unaware of the history of noble gases, they were at one time known as inert gases because chemists thought their full outer shell of electrons made them unreactive. As more and more reactions for these so-called inert gases were discovered, it became necessary to abandon the “inert” label and focus on their nobility.

A neon light is not really much more than a fluorescent tube (actually, it’s less as it needs no phosphor coating on the inside), neon tubes contain the noble gas neon, surprise, surprise. Pass an electric discharge through a tube containing low pressure neon and it will glow with that familiar orange-red glow, so evocative of late-night bars and sleazy movies.

A neon light uses a very high voltage to propel an electric current through a low-density gas of neon atoms held in a glass tube. Charges from the electrode at each end of the tube fly through the gas colliding frequently with neon atoms and transferring some of their energy to the neon atoms. This kicks the neon atoms into a higher energy, excited state, with an electron in a higher orbital than normal. This excited state does not last and as the electron loses energy the atom drops back to a lower energy state and releases a photon of light. The energy of this photon is equivalent to the energy fall and for neon atoms that coincides with an energy that produces a reddish glow.

Many people, unfamiliar with the noble gas group of the periodic table – the p-block, assume that all coloured fluorescent tubes used in signage are neon signs. However, there are two ways to produce other colours – paint a standard mercury tube with the colour you want or far more effectively use a different noble gas in the tube instead of neon, perhaps together with mercury vapour to give a stronger glow. Here’s a break down of the discharge colours for each noble gas.

Helium (He) – Orangey white, usually
Neon (Ne) – Orange-red glow
Argon (Ar) – Violet, pale lavender blue
Krypton (Kr) – Grayish dim off-white
Xenon (Xe) – Blue-grey
Radon (Rn) – radioactive, not used in lighting

Of course, it is not only the noble gases and mercury vapour that can be added to lighting tubes. Nitrogen produces a slightly pinker glow than argon, oxygen glows violet-lavender but dimly. Hydrogen glows lavender at low currents, but pinkish magenta above 10 milliAmps, while carbon dioxide produces a slight bluish-white. Mercury can be made to glow in the ultraviolet, and is used in so-called black lights. Sodium vapour at low pressure glows the bright yellow of street lighting, particularly in England. And, even water vapour produces a glow similar to hydrogen, only dimmer .

The Future

Pundits are predicting that the first computer that will be at least as intelligent as a human will be built in 2010 and by 2049 a $1000 computer will outsmart the entire human race. But, this video is about more than that.

It tracks the shifts that are occurring today and extrapolates them into implications for those currently in high school and higher education. Think about it, if you start a technical degree this year, half of what you learn in that four-year course will be outdated before you reach the end of the third year. After all, it took radio 38 years to reach a 50 million audience, television 13 years, the internet 4 years, and Facebook achieved a market penetration that size in just 2 years.

In 1984, the year I started university, there were 1000 internet devices around the world (I certainly didn’t send an email till more than four years after that). By 1992, that number was 1,000,000. Today, there are at least a billion internet devices and that number will inevitably rise as people with at least one personal computer augment their connectivity with more and more mobile devices, such as smart phones, android phones, tablets, slates, iPads, iPods iPhones etc.

The video was produced by the zyOzy Foundation, which believes that the themes in the “Did You Know?” video are global in nature and apply to schools and children around the world.